A NHC-silyliumylidene cation for catalytic N‑formylation of amines using carbon dioxide

A NHC-silyliumylidene cation for catalytic N‑formylation of amines using carbon dioxide

This study describes the use of a silicon(II) complex, namely, the NHC-silyliumylidene cation complex [(I ) SiH]I (1, I =:C{N(Me)C(Me)} ), to catalyze the chemoselective N-formylation of primary and secondary amines using CO and PhSiH under mild conditions to afford the corresponding formamides a...

Cur síos iomlán

Sonraí bibleagrafaíochta
Príomhchruthaitheoirí: Leong, Bi-Xiang, Teo, Yeow-Chuan, Condamines, Cloé, Yang, Ming-Chung, Su, Ming-Der, So, Cheuk-Wai
Rannpháirtithe: School of Physical and Mathematical Sciences
Formáid: Journal Article
Teanga:English
Foilsithe / Cruthaithe: 2021
Ábhair:
Science::Chemistry::Organic chemistry
Mixtures
Catalysts
Rochtain ar líne:https://hdl.handle.net/10356/149731

Ar líne

https://hdl.handle.net/10356/149731

Míreanna comhchosúla