A NHC-silyliumylidene cation for catalytic N‑formylation of amines using carbon dioxide

A NHC-silyliumylidene cation for catalytic N‑formylation of amines using carbon dioxide

This study describes the use of a silicon(II) complex, namely, the NHC-silyliumylidene cation complex [(I ) SiH]I (1, I =:C{N(Me)C(Me)} ), to catalyze the chemoselective N-formylation of primary and secondary amines using CO and PhSiH under mild conditions to afford the corresponding formamides a...

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Bibliographic Details
Main Authors: Leong, Bi-Xiang, Teo, Yeow-Chuan, Condamines, Cloé, Yang, Ming-Chung, Su, Ming-Der, So, Cheuk-Wai
Other Authors: School of Physical and Mathematical Sciences
Format: Journal Article
Language:English
Published: 2021
Subjects:
Science::Chemistry::Organic chemistry
Mixtures
Catalysts
Online Access:https://hdl.handle.net/10356/149731

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