Aluminum-hydride-catalyzed hydroboration of carbon dioxide
This study describes the first use of a bis(phosphoranyl)methanido aluminum hydride, [ClC(PPh2NMes)2AlH2] (2, Mes = Me3C6H2), for the catalytic hydroboration of CO2. Complex 2 was synthesized by the reaction of a lithium carbenoid [Li(Cl)C(PPh2NMes)2] with 2 equiv of AlH3·NEtMe2 in toluene at -78 °C...
| Автори: | , , , , , , , |
|---|---|
| Інші автори: | |
| Формат: | Journal Article |
| Мова: | English |
| Опубліковано: |
2021
|
| Предмети: | |
| Онлайн доступ: | https://hdl.handle.net/10356/151886 |