Carbene-catalyzed atroposelective synthesis of axially chiral styrenes

Carbene-catalyzed atroposelective synthesis of axially chiral styrenes

Axially chiral styrenes bearing a chiral axis between a sterically non-congested acyclic alkene and an aryl ring are difficult to prepare due to low rotational barrier of the axis. Disclosed here is an N-heterocyclic carbene (NHC) catalytic asymmetric solution to this problem. Our reaction involves...

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Bibliographic Details
Main Authors: Yan, Jia-Lei, Maiti, Rakesh, Ren, Shi-Chao, Tian, Weiyi, Li, Tingting, Xu, Jun, Mondal, Bivas, Jin, Zhichao, Chi, Robin Yonggui
Other Authors: School of Physical and Mathematical Sciences
Format: Journal Article
Language:English
Published: 2022
Subjects:
Science::Chemistry
Acetylene
Alkene
Online Access:https://hdl.handle.net/10356/155056

Internet

https://hdl.handle.net/10356/155056

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