Umpolung of donor-acceptor cyclopropanes : via N-heterocyclic carbene organic catalysis

Umpolung of donor-acceptor cyclopropanes : via N-heterocyclic carbene organic catalysis

A carbene-catalyzed formal umpolung of donor-acceptor (D-A) cyclopropanes is disclosed. The cyclopropane moiety is connected to an acetyl aldehyde that can be activated by a carbene catalyst. The initially electrophilic carbon attached to the donor group of the D-A cyclopropane aldehyde is inverted...

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Bibliographic Details
Main Authors: Nie, Guihua, Huang, Xuan, Wang, Zhongyao, Pan,Dingwu, Zhang, Junmin, Chi, Robin Yonggui
Other Authors: School of Physical and Mathematical Sciences
Format: Journal Article
Language:English
Published: 2022
Subjects:
Science::Chemistry
Aldehydes
Catalysis
Online Access:https://hdl.handle.net/10356/155078

Internet

https://hdl.handle.net/10356/155078

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