Atomic layer deposition of metallic tri-layer for alloy formation

Research has brought about great interest in the field of thin films and its applications. With the need for increasingly smaller devices, there is an increasing demand for synthesis methods to control and precisely fabricate components and materials. Atomic layer deposition (ALD) has become a topic...

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Main Author: Yong, Sidney Kwong Roong
Other Authors: Alfred Tok Iing Yoong
Format: Final Year Project (FYP)
Language:English
Published: Nanyang Technological University 2022
Subjects:
Online Access:https://hdl.handle.net/10356/156175
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author Yong, Sidney Kwong Roong
author2 Alfred Tok Iing Yoong
author_facet Alfred Tok Iing Yoong
Yong, Sidney Kwong Roong
author_sort Yong, Sidney Kwong Roong
collection NTU
description Research has brought about great interest in the field of thin films and its applications. With the need for increasingly smaller devices, there is an increasing demand for synthesis methods to control and precisely fabricate components and materials. Atomic layer deposition (ALD) has become a topic of interest owing to its high compositional control, down to the atomic level. The technique allows for high quality production of films with good uniformity, and linearity of thickness control based on the number of deposition cycles. In this paper, we studied the deposition of metallic tri-layer consisting of Platinum (Pt), Iridium (Ir), and Palladium (Pd), which was synthesized using ALD. The metal layers were deposited on Sapphire (Al2O3) with ozone as a reactive agent. The process was shown to be promising in producing thin films with precise composition, thickness control, and uniformity, which was proven with characterization techniques such as X-ray Diffraction (XRD), X-ray Photoelectron Spectroscopy (XPS), and Energy dispersive X-ray (EDX). After achieving a successful tri-metallic layer deposition, the substrate and deposited layers are put through the alloying process of carbothermal shock (CTS). This work provides novel insights to the synthesis of tri-metallic alloys through the combination of atomic layer deposition (ALD) and Carbothermal shock (CTS) alloying, opening possibilities for the furthered research of high entropy alloys synthesis methods.
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spelling ntu-10356/1561752022-04-09T14:35:30Z Atomic layer deposition of metallic tri-layer for alloy formation Yong, Sidney Kwong Roong Alfred Tok Iing Yoong School of Materials Science and Engineering MIYTok@ntu.edu.sg Engineering::Materials Research has brought about great interest in the field of thin films and its applications. With the need for increasingly smaller devices, there is an increasing demand for synthesis methods to control and precisely fabricate components and materials. Atomic layer deposition (ALD) has become a topic of interest owing to its high compositional control, down to the atomic level. The technique allows for high quality production of films with good uniformity, and linearity of thickness control based on the number of deposition cycles. In this paper, we studied the deposition of metallic tri-layer consisting of Platinum (Pt), Iridium (Ir), and Palladium (Pd), which was synthesized using ALD. The metal layers were deposited on Sapphire (Al2O3) with ozone as a reactive agent. The process was shown to be promising in producing thin films with precise composition, thickness control, and uniformity, which was proven with characterization techniques such as X-ray Diffraction (XRD), X-ray Photoelectron Spectroscopy (XPS), and Energy dispersive X-ray (EDX). After achieving a successful tri-metallic layer deposition, the substrate and deposited layers are put through the alloying process of carbothermal shock (CTS). This work provides novel insights to the synthesis of tri-metallic alloys through the combination of atomic layer deposition (ALD) and Carbothermal shock (CTS) alloying, opening possibilities for the furthered research of high entropy alloys synthesis methods. Bachelor of Engineering (Materials Engineering) 2022-04-06T04:44:16Z 2022-04-06T04:44:16Z 2022 Final Year Project (FYP) Yong, S. K. R. (2022). Atomic layer deposition of metallic tri-layer for alloy formation. Final Year Project (FYP), Nanyang Technological University, Singapore. https://hdl.handle.net/10356/156175 https://hdl.handle.net/10356/156175 en application/pdf Nanyang Technological University
spellingShingle Engineering::Materials
Yong, Sidney Kwong Roong
Atomic layer deposition of metallic tri-layer for alloy formation
title Atomic layer deposition of metallic tri-layer for alloy formation
title_full Atomic layer deposition of metallic tri-layer for alloy formation
title_fullStr Atomic layer deposition of metallic tri-layer for alloy formation
title_full_unstemmed Atomic layer deposition of metallic tri-layer for alloy formation
title_short Atomic layer deposition of metallic tri-layer for alloy formation
title_sort atomic layer deposition of metallic tri layer for alloy formation
topic Engineering::Materials
url https://hdl.handle.net/10356/156175
work_keys_str_mv AT yongsidneykwongroong atomiclayerdepositionofmetallictrilayerforalloyformation