Lewis pair polymerization of alkyl methacrylate by amidinato silicon compounds and Tris(pentafluorophenyl)borane
0.5 mol% of the amidinato disilyne [LSi:]2 (1, L = PhC(NtBu)2) and 1 mol% of B(C6F5)3 cooperatively polymerized methyl methacrylate (MMA) to form poly(MMA) with the H and CH2C(=CH2)COMe end groups (P1, Mn = 3.1 ×103 gmol-1; repeating unit, n = 31; polydispersity index, Đ: 1.55). The catalytic mechan...
| Main Authors: | , , , , , |
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| 其他作者: | |
| 格式: | Journal Article |
| 语言: | English |
| 出版: |
2022
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| 主题: | |
| 在线阅读: | https://hdl.handle.net/10356/157594 |