Carbene-catalyzed enantioselective sulfonylation of enone aryl aldehydes: a new mode of breslow intermediate oxidation

A carbene-catalyzed sulfonylation reaction between enone aryl aldehydes and sulfonyl chlorides is disclosed. The reaction effectively installs sulfone moieties in a highly enantioselective manner to afford sulfone-containing bicyclic lactones. The sulfonyl chloride behaves both as an oxidant and a n...

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Detalhes bibliográficos
Principais autores: Deng, Rui, Wu, Shuquan, Mou, Chengli, Liu, Jianjian, Zheng, Pengcheng, Zhang, Xinglong, Chi, Robin Yonggui
Outros Autores: School of Physical and Mathematical Sciences
Formato: Journal Article
Idioma:English
Publicado em: 2022
Assuntos:
Acesso em linha:https://hdl.handle.net/10356/161331