Organobase-catalyzed umpolung of amides: the generation and transfer of carbamoyl anion

A novel organobase-catalyzed umpolung reaction of amides was disclosed. This method provides an efficient method to generate and transfer carbamoyl anions. In this transformation, some of the inherent disadvantages of carbamoyl metal were avoided. The mechanistic analysis revealed that the reaction...

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Bibliographic Details
Main Authors: Li, Qi, Zhang, Wang, Zhu, Chen, Pan, Hong, Shi, Kang-Yue, Zhang, Yicheng, Han, Man-Yi, Tan, Choon-Hong
Other Authors: School of Chemistry, Chemical Engineering and Biotechnology
Format: Journal Article
Language:English
Published: 2023
Subjects:
Online Access:https://hdl.handle.net/10356/168937