Tetrakis(N-heterocyclic carbene)-diboron(0): double single-electron-transfer reactivity
The use of 1,3,4,5-tetramethylimidazol-2-ylidene (IMe) to coordinate with diatomic B2 species afforded a tetrakis(N-heterocyclic carbene)-diboron(0) [(IMe)2B-B(IMe)2] (2). The singly bonded B2 moiety therein possesses a valence electronic configuration 1σg21πu21πg*2 with four vacant molecular orbita...
| Main Authors: | , , , , , , , |
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| 其他作者: | |
| 格式: | Journal Article |
| 语言: | English |
| 出版: |
2023
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| 主题: | |
| 在线阅读: | https://hdl.handle.net/10356/169919 |