Single-nitrogen atom incorporation into B=B bond via the N=N bond splitting of diazo compound and diazirine
Triboraazabutenyne 3 is synthesized by the reaction of diboraazabutenyne 1 with aryl boron dibromide followed by the reduction. The ligand exchange to replace phosphine on the terminal sp2 B atom with carbene furnishes 4. 11 B NMR, solid-state structures, and computational studies disclose that 3 an...
| Main Authors: | , |
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| 格式: | Journal Article |
| 语言: | English |
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2023
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| 在线阅读: | https://hdl.handle.net/10356/171089 |