Single-nitrogen atom incorporation into B=B bond via the N=N bond splitting of diazo compound and diazirine

Triboraazabutenyne 3 is synthesized by the reaction of diboraazabutenyne 1 with aryl boron dibromide followed by the reduction. The ligand exchange to replace phosphine on the terminal sp2 B atom with carbene furnishes 4. 11 B NMR, solid-state structures, and computational studies disclose that 3 an...

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Main Authors: Zhu, Lizhao, Kinjo, Rei
其他作者: School of Chemistry, Chemical Engineering and Biotechnology
格式: Journal Article
语言:English
出版: 2023
主题:
在线阅读:https://hdl.handle.net/10356/171089