Synergistic copper-aminocatalysis for direct tertiary 𝜶-alkylation of ketones with electron-deficient alkanes

Synergistic copper-aminocatalysis for direct tertiary 𝜶-alkylation of ketones with electron-deficient alkanes

In this study, a novel approach for the tertiary α-alkylation of ketones using alkanes with electron-deficient C─H bonds is presented, employing a synergistic catalytic system combining inexpensive copper salts with aminocatalysis. This methodology addresses the limitations of traditional alkylation...

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Bibliografiske detaljer
Main Authors: Shan, Qi-Chao, Wu, You-Wei, Chen, Mu-Xiang, Zhao, Xuefei, Loh, Teck-Peng, Hu, Xu-Hong
Andre forfattere: School of Chemistry, Chemical Engineering and Biotechnology
Format: Journal Article
Sprog:English
Udgivet: 2024
Fag:
Chemistry
Ketones
Tertiary alkylation
Online adgang:https://hdl.handle.net/10356/178845

Internet

https://hdl.handle.net/10356/178845

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