Catalytic synthesis of azeheterocycles from organic azides.
One electron oxidation of bicyclic cyclopropanol, bicyclo[4.1.0]heptan-1-ol by a catalytic amount of Mn(III) promotes ring-expansion to afford 7-membered-ring β-carbonyl radical, which adds to vinyl azide to form an iminyl radical with elimination of dinitrogen. Iminyl radical then cyclizes with a...
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| Format: | Final Year Project (FYP) |
| Language: | English |
| Published: |
2010
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| Online Access: | http://hdl.handle.net/10356/38933 |