Asymmetric ligand transformation reactions promoted by cyclometallated complexes
Complex bis(u-chloro)-bis{(R)-1-(dimethylamino)ethyl] naphtyl-C2,N} palladium (II) was found to successfully undergo insertion reactions at the palladium-carbon with the diphenylarsinoprop-1-yne ligand at room temperature which leads to the formation of a new 7-membered metallacyce in the inserted p...
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Format: | Thesis |
Language: | English |
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2012
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Online Access: | https://hdl.handle.net/10356/47715 |