Metal 1,3-Benzobis(thiophosphinoyl)methanediide complexes and a base-stabilized 2-silaallene derivative
The syntheses of metal bis(thiophosphinoyl) and 1,3-benzobis(thiophosphinoyl)methanediide complexes are reported. The reaction of bis(thiophosphinoyl)methane [CH2(Ph2P=S)2] with 1 equivalent of KOtBu and 1.2 equivalent of nBuLi, followed by the hydrolysis to form the 1,3-benzobis(thiophosphinoyl)met...
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| Format: | Thesis |
| Language: | English |
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2013
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| Online Access: | http://hdl.handle.net/10356/53520 |