Part I: N-heterocyclic carbene catalyzed homoenolate addition of enals to nitroalkenes. Part II: Palladium catalyzed N-heterocyclic glycosides synthesis
Part 1. N-heterocyclic carbene catalyzed highly diastereoselective and potentially multifunctional nitroester from α,β-unsaturated aldehyde and nitrodiene is described. Amongst the imidazolium carbene catalysts tested, sterically demanding 1,3-bis(2,6-diisopropyl phenyl)imidazolium chloride gave the...
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| Format: | Thesis |
| Language: | English |
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2015
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| Online Access: | http://hdl.handle.net/10356/62906 |