Part I: Asymmetric intermolecular Heck reaction of aryl halides. Part II: Asymmetric addition of organoboroxines to common enones and imines using copper catalysts
We developed a mild reaction for asymmetric Heck reaction of aryl bromides and chlorides with cyclic olefins. This is the first time that asymmetric intermolecular Heck reactions of aryl halides were realized in high ee. Ammonium salts and alcohol solvent were employed as hydrogen-bonding donors to...
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| Format: | Thesis |
| Language: | English |
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2016
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| Online Access: | https://hdl.handle.net/10356/69181 |