Part I : Palladium-catalyzed radical alkylation of arenes. Part II : Nickel-catalyzed asymmetric hydrogenation of quinoxalines using formic acid
We developed a general procedure for palladium-catalyzed radical alkylation of activated arenes. Electron-deficient benzenes and naphthalene derivatives reacted to give alkylated products in moderate to good yields. The alkyl radicals added to para position of strong electron-withdrawing groups on t...
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| Format: | Thesis |
| Language: | English |
| Published: |
2017
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| Online Access: | http://hdl.handle.net/10356/69709 |