Part I : Palladium-catalyzed radical alkylation of arenes. Part II : Nickel-catalyzed asymmetric hydrogenation of quinoxalines using formic acid

We developed a general procedure for palladium-catalyzed radical alkylation of activated arenes. Electron-deficient benzenes and naphthalene derivatives reacted to give alkylated products in moderate to good yields. The alkyl radicals added to para position of strong electron-withdrawing groups on t...

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Bibliographic Details
Main Author: Lim, Li Hui
Other Authors: Zhou Jianrong
Format: Thesis
Language:English
Published: 2017
Subjects:
Online Access:http://hdl.handle.net/10356/69709