Development of phosphapalladacycles as potential catalysts for asymmetric synthesis
A series of chiral tertiary phosphine ligands have been prepared via two synthetic approaches, namely through the optical resolution of racemic phosphines, and the asymmetric hydrophosphination reaction of enones with secondary phosphines promoted by chiral palladacycles. The ortho-palladation of th...
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Format: | Thesis |
Language: | English |
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2017
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Online Access: | http://hdl.handle.net/10356/72660 |