Synthesis, structural studies and ligand influence on the stability of aryl-NHC stabilised trimethylaluminium complexes

Synthesis, structural studies and ligand influence on the stability of aryl-NHC stabilised trimethylaluminium complexes

Treatment of a series of aromatic NHCs (IMes, SIMes, IPr and SIPr) with trimethylaluminium produced their corresponding Lewis acid–base adducts: IMes·AlMe3 (1), SIMes·AlMe3 (2), IPr·AlMe3 (3), and SIPr·AlMe3 (4). These complexes expand the few known examples of saturated NHC stabilised Group 13 comp...

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Bibliographic Details
Main Authors: Wu, Melissa M., Gill, Arran M., Lu, Yunpeng, Laura, Falivene, Li, Yongxin, Rakesh, Ganguly, Luigi, Cavallo, Felipe, García
Other Authors: School of Physical and Mathematical Sciences
Format: Journal Article
Language:English
Published: 2016
Subjects:
Ligands
Trimethylaluminium
Online Access:https://hdl.handle.net/10356/82664
http://hdl.handle.net/10220/40280

Internet

https://hdl.handle.net/10356/82664
http://hdl.handle.net/10220/40280

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