Synthesis, structural studies and ligand influence on the stability of aryl-NHC stabilised trimethylaluminium complexes
Treatment of a series of aromatic NHCs (IMes, SIMes, IPr and SIPr) with trimethylaluminium produced their corresponding Lewis acid–base adducts: IMes·AlMe3 (1), SIMes·AlMe3 (2), IPr·AlMe3 (3), and SIPr·AlMe3 (4). These complexes expand the few known examples of saturated NHC stabilised Group 13 comp...
Main Authors: | Wu, Melissa M., Gill, Arran M., Lu, Yunpeng, Laura, Falivene, Li, Yongxin, Rakesh, Ganguly, Luigi, Cavallo, Felipe, García |
---|---|
Other Authors: | School of Physical and Mathematical Sciences |
Format: | Journal Article |
Language: | English |
Published: |
2016
|
Subjects: | |
Online Access: | https://hdl.handle.net/10356/82664 http://hdl.handle.net/10220/40280 |
Similar Items
-
Platinum-osmium heterometallic clusters containing N-heterocyclic carbene ligands and an electron-deficient tetraosmium by-product
by: Liu, Yu, et al.
Published: (2020) -
Ligand effect on switching the rate-determining step of water oxidation in atomically precise metal nanoclusters
by: Liu, Zhihe, et al.
Published: (2023) -
Bay-region functionalisation of Ar-BIAN ligands and their use within highly absorptive cationic iridium(III) dyes
by: Kamrul Hasan, et al.
Published: (2018) -
Amino-functionalised β-diketiminate ligands (N-nacnacs): Synthesis and coordination chemistry with Main Group elements
by: Huan, D
Published: (2018) -
Amidinato Isopropylmethylamidosilylene-catalyzed hydroboration of carbonyl compounds
by: Lee, Jiawen, et al.
Published: (2022)