Catalytic enhancement of gold nanocages induced by undercoordination-charge-polarization
Principle behind the highest catalytic ability of the least coordinated gold remains a puzzle. With the aid of density functional theory calculations, we show that in 3-coordinated gold cages (i) the Au–Au bond contracts by 5% in average, (ii) the valance density-of-states shift up to Fermi level w...
| Hoofdauteurs: | , , , , |
|---|---|
| Andere auteurs: | |
| Formaat: | Journal Article |
| Taal: | English |
| Gepubliceerd in: |
2017
|
| Onderwerpen: | |
| Online toegang: | https://hdl.handle.net/10356/83363 http://hdl.handle.net/10220/42552 |