Carbene-catalyzed reductive coupling of nitrobenzyl bromide and nitroalkene via the single-electron-transfer (SET) process and formal 1,4-addition

A carbene-catalyzed reductive 1,4-addition of nitrobenzyl bromides to nitroalkenes is disclosed. The reaction proceeds via a carbene-enabled single-electron-transfer process that generates radicals as key intermediates. The present study expands the potentials of carbene catalysis and offers unusual...

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Bibliographic Details
Main Authors: Wang, Yuhuang, Du, Yu, Huang, Xuan, Wu, Xingxing, Zhang, Yuexia, Yang, Song, Chi, Robin Yonggui
Other Authors: School of Physical and Mathematical Sciences
Format: Journal Article
Language:English
Published: 2017
Subjects:
Online Access:https://hdl.handle.net/10356/85595
http://hdl.handle.net/10220/43776