Polyhalides as efficient and mild oxidants for oxidative carbene organocatalysis by radical processes
Simple and inexpensive polyhalides (CCl4 and C2Cl6 ) have been found to be effective and versatile oxidants in removing electrons from Breslow intermediates under N-heterocyclic carbene (NHC) catalysis. This oxidative reaction involves multiple single-electron-transfer (SET) processes and several ra...
Main Authors: | , , , , , , , , |
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Other Authors: | |
Format: | Journal Article |
Language: | English |
Published: |
2017
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Subjects: | |
Online Access: | https://hdl.handle.net/10356/85610 http://hdl.handle.net/10220/43775 |