Mechanistic insights for the photoredox organocatalytic fluorination of aliphatic carbons by anthraquinone using time-resolved and DFT studies

Chemoselective photoredox fluorination is an appealing approach to access fluorinated fine chemicals such as active pharmaceutical ingredients, but most of the known procedures currently lack time-resolved mechanistic insights. We use nanosecond transient absorption spectroscopy and density function...

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Bibliographic Details
Main Authors: Kee, J. W., Shao, H., Kee, C. W., Lu, Yunpeng, Soo, Han Sen, Tan, Choon Hong
Other Authors: School of Physical and Mathematical Sciences
Format: Journal Article
Language:English
Published: 2018
Subjects:
Online Access:https://hdl.handle.net/10356/87664
http://hdl.handle.net/10220/47035