Charging mechanism in a SiO2 matrix embedded with Si nanocrystals

One of the applications of a Si nanocrystals (nc-Si) embedded in a SiO2 matrix is in the area of nonvolatile memory devices based on the charge storage in the material system. However, whether the charge trapping mainly occurs at the nc-Si/SiO2 interface or in the nc-Si is still unclear. In this wor...

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Main Authors: Fu, Yong Qing, Liu, Yang, Chen, Tupei, Ding, Liang, Zhang, Sam, Fung, Stevenson Hon Yuen
Other Authors: School of Electrical and Electronic Engineering
Format: Journal Article
Language:English
Published: 2010
Subjects:
Online Access:https://hdl.handle.net/10356/91838
http://hdl.handle.net/10220/6404
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author Fu, Yong Qing
Liu, Yang
Chen, Tupei
Ding, Liang
Zhang, Sam
Fung, Stevenson Hon Yuen
author2 School of Electrical and Electronic Engineering
author_facet School of Electrical and Electronic Engineering
Fu, Yong Qing
Liu, Yang
Chen, Tupei
Ding, Liang
Zhang, Sam
Fung, Stevenson Hon Yuen
author_sort Fu, Yong Qing
collection NTU
description One of the applications of a Si nanocrystals (nc-Si) embedded in a SiO2 matrix is in the area of nonvolatile memory devices based on the charge storage in the material system. However, whether the charge trapping mainly occurs at the nc-Si/SiO2 interface or in the nc-Si is still unclear. In this work, by x-ray photoemission spectroscopy analysis of the Si 2p peaks, the concentrations of both the nc-Si and the Si suboxides that exist at the nc-Si/SiO2 interface are determined as a function of thermal annealing, and the charging effect is also measured by monitoring the shift of the surface C 1s peak. It is observed that the annealing-caused reduction of the total concentration of the interfacial suboxides is much faster than that of both the C 1s shift and the nc-Si concentration. In addition, the trend of the C 1s shift coincides with that of the nc-Si concentration. The results suggest that the Si nanocrystal, rather than the nc-Si/SiO2 interface, plays the dominant role in the charging effect.
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spelling ntu-10356/918382020-03-07T13:57:27Z Charging mechanism in a SiO2 matrix embedded with Si nanocrystals Fu, Yong Qing Liu, Yang Chen, Tupei Ding, Liang Zhang, Sam Fung, Stevenson Hon Yuen School of Electrical and Electronic Engineering DRNTU::Engineering::Electrical and electronic engineering DRNTU::Engineering::Mechanical engineering One of the applications of a Si nanocrystals (nc-Si) embedded in a SiO2 matrix is in the area of nonvolatile memory devices based on the charge storage in the material system. However, whether the charge trapping mainly occurs at the nc-Si/SiO2 interface or in the nc-Si is still unclear. In this work, by x-ray photoemission spectroscopy analysis of the Si 2p peaks, the concentrations of both the nc-Si and the Si suboxides that exist at the nc-Si/SiO2 interface are determined as a function of thermal annealing, and the charging effect is also measured by monitoring the shift of the surface C 1s peak. It is observed that the annealing-caused reduction of the total concentration of the interfacial suboxides is much faster than that of both the C 1s shift and the nc-Si concentration. In addition, the trend of the C 1s shift coincides with that of the nc-Si concentration. The results suggest that the Si nanocrystal, rather than the nc-Si/SiO2 interface, plays the dominant role in the charging effect. Published version 2010-09-06T01:41:27Z 2019-12-06T18:12:50Z 2010-09-06T01:41:27Z 2019-12-06T18:12:50Z 2006 2006 Journal Article Liu, Y., Chen, T. P., Ding, L., Zhang, S., Fu, Y. Q., & Fung, S. H. Y., (2006). Charging mechanism in a SiO2 matrix embedded with Si nanocrystals. Journal of Applied Physics, 100, 1-3. 0021-8979 https://hdl.handle.net/10356/91838 http://hdl.handle.net/10220/6404 10.1063/1.2374929 en Journal of applied physics Journal of Applied Physics © copyright 2006 American Institute of Physics. The journal's website is located at http://jap.aip.org/japiau/v100/i9/p096111_s1?isAuthorized=no 3 p. application/pdf
spellingShingle DRNTU::Engineering::Electrical and electronic engineering
DRNTU::Engineering::Mechanical engineering
Fu, Yong Qing
Liu, Yang
Chen, Tupei
Ding, Liang
Zhang, Sam
Fung, Stevenson Hon Yuen
Charging mechanism in a SiO2 matrix embedded with Si nanocrystals
title Charging mechanism in a SiO2 matrix embedded with Si nanocrystals
title_full Charging mechanism in a SiO2 matrix embedded with Si nanocrystals
title_fullStr Charging mechanism in a SiO2 matrix embedded with Si nanocrystals
title_full_unstemmed Charging mechanism in a SiO2 matrix embedded with Si nanocrystals
title_short Charging mechanism in a SiO2 matrix embedded with Si nanocrystals
title_sort charging mechanism in a sio2 matrix embedded with si nanocrystals
topic DRNTU::Engineering::Electrical and electronic engineering
DRNTU::Engineering::Mechanical engineering
url https://hdl.handle.net/10356/91838
http://hdl.handle.net/10220/6404
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