Enantioselective oxidative cross-dehydrogenative coupling of tertiary amines to aldehydes

An enantioselective and direct oxidative coupling of aldehydes to tertiary amines to give β-amino alcohols is described. Catalyzed by copper(II), the reaction proceeds to give a racemic mixture of products; however, by using a combination of copper(II) and a chiral amine catalyst, the reaction gives...

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Main Authors: Zhang, Junmin, Tiwari, Bhoopendra, Xing, Chong, Chen, Xingkuan, Chi, Robin Yonggui
其他作者: School of Physical and Mathematical Sciences
格式: Journal Article
語言:English
出版: 2012
主題:
在線閱讀:https://hdl.handle.net/10356/94637
http://hdl.handle.net/10220/8116