Arene CH=O hydrogen bonding : a stereocontrolling tool in palladium-catalyzed arylation and vinylation of ketones

Arene CH=O hydrogen bonding : a stereocontrolling tool in palladium-catalyzed arylation and vinylation of ketones

Weak is powerful: For the arylation of tin enolates, the palladium catalyst engages in weak CH=O hydrogen bonds to control stereoselectivity (see scheme). Similar catalysts capable of NH=O hydrogen bonding also works well.

Bibliographic Details
Main Authors: Huang, Zhiyan, Lim, Li Hui, Chen, Zuliang, Li, Yongxin, Zhou, Feng, Su, Haibin, Zhou, Jianrong Steve
Other Authors: School of Materials Science & Engineering
Format: Journal Article
Language:English
Published: 2013
Online Access:https://hdl.handle.net/10356/99248
http://hdl.handle.net/10220/17600

Internet

https://hdl.handle.net/10356/99248
http://hdl.handle.net/10220/17600

Similar Items