Arene CH=O hydrogen bonding : a stereocontrolling tool in palladium-catalyzed arylation and vinylation of ketones
Weak is powerful: For the arylation of tin enolates, the palladium catalyst engages in weak CH=O hydrogen bonds to control stereoselectivity (see scheme). Similar catalysts capable of NH=O hydrogen bonding also works well.
| Main Authors: | , , , , , , |
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| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2013
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| Online Access: | https://hdl.handle.net/10356/99248 http://hdl.handle.net/10220/17600 |
| _version_ | 1811682390175645696 |
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| author | Huang, Zhiyan Lim, Li Hui Chen, Zuliang Li, Yongxin Zhou, Feng Su, Haibin Zhou, Jianrong Steve |
| author2 | School of Materials Science & Engineering |
| author_facet | School of Materials Science & Engineering Huang, Zhiyan Lim, Li Hui Chen, Zuliang Li, Yongxin Zhou, Feng Su, Haibin Zhou, Jianrong Steve |
| author_sort | Huang, Zhiyan |
| collection | NTU |
| description | Weak is powerful: For the arylation of tin enolates, the palladium catalyst engages in weak CH=O hydrogen bonds to control stereoselectivity (see scheme). Similar catalysts capable of NH=O hydrogen bonding also works well. |
| first_indexed | 2024-10-01T03:56:04Z |
| format | Journal Article |
| id | ntu-10356/99248 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T03:56:04Z |
| publishDate | 2013 |
| record_format | dspace |
| spelling | ntu-10356/992482020-06-01T10:01:33Z Arene CH=O hydrogen bonding : a stereocontrolling tool in palladium-catalyzed arylation and vinylation of ketones Huang, Zhiyan Lim, Li Hui Chen, Zuliang Li, Yongxin Zhou, Feng Su, Haibin Zhou, Jianrong Steve School of Materials Science & Engineering School of Physical and Mathematical Sciences Weak is powerful: For the arylation of tin enolates, the palladium catalyst engages in weak CH=O hydrogen bonds to control stereoselectivity (see scheme). Similar catalysts capable of NH=O hydrogen bonding also works well. 2013-11-12T05:38:45Z 2019-12-06T20:05:02Z 2013-11-12T05:38:45Z 2019-12-06T20:05:02Z 2013 2013 Journal Article 1433-7851 https://hdl.handle.net/10356/99248 http://hdl.handle.net/10220/17600 10.1002/anie.201300621 en Angewandte chemie international edition © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim |
| spellingShingle | Huang, Zhiyan Lim, Li Hui Chen, Zuliang Li, Yongxin Zhou, Feng Su, Haibin Zhou, Jianrong Steve Arene CH=O hydrogen bonding : a stereocontrolling tool in palladium-catalyzed arylation and vinylation of ketones |
| title | Arene CH=O hydrogen bonding : a stereocontrolling tool in palladium-catalyzed arylation and vinylation of ketones |
| title_full | Arene CH=O hydrogen bonding : a stereocontrolling tool in palladium-catalyzed arylation and vinylation of ketones |
| title_fullStr | Arene CH=O hydrogen bonding : a stereocontrolling tool in palladium-catalyzed arylation and vinylation of ketones |
| title_full_unstemmed | Arene CH=O hydrogen bonding : a stereocontrolling tool in palladium-catalyzed arylation and vinylation of ketones |
| title_short | Arene CH=O hydrogen bonding : a stereocontrolling tool in palladium-catalyzed arylation and vinylation of ketones |
| title_sort | arene ch o hydrogen bonding a stereocontrolling tool in palladium catalyzed arylation and vinylation of ketones |
| url | https://hdl.handle.net/10356/99248 http://hdl.handle.net/10220/17600 |
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