σ-Bond metathesis between M–X and RC(O)X′ (M = Pt, Pd; X, X′ = Cl, Br, I) : facile determination of the relative ΔG values of the oxidative additions of RC(O)X to an M(0) complex, evidence by density functional theory calculations, and synthetic applications

σ-Bond metathesis between M–X and RC(O)X′ (M = Pt, Pd; X, X′ = Cl, Br, I) : facile determination of the relative ΔG values of the oxidative additions of RC(O)X to an M(0) complex, evidence by density functional theory calculations, and synthetic applications

The novel utility of the ligand exchange reaction between M–X and RC(O)X′ (X, X′ = halogen; R = aryl, alkyl) is described. The relative ΔGs (ΔΔGs) of the oxidative additions of acid halides RC(O)X to M(PPh3)2Ln (M = Pt, Pd) were determined using the halogen-exchange reactions between X of trans-M(X)...

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Bibliographic Details
Main Authors: Kuniyasu, Hitoshi, Sanagawa, Atsushi, Nakane, Daisuke, Iwasaki, Takanori, Kambe, Nobuaki, Bobuatong, Karan, Lu, Yunpeng, Ehara, Masahiro
Other Authors: School of Physical and Mathematical Sciences
Format: Journal Article
Language:English
Published: 2013
Subjects:
DRNTU::Science::Mathematics::Applied mathematics
Online Access:https://hdl.handle.net/10356/99939
http://hdl.handle.net/10220/16543

Internet

https://hdl.handle.net/10356/99939
http://hdl.handle.net/10220/16543

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