A FeCl(3)-promoted highly atropodiastereoselective cascade reaction: synthetic utility of radical cations in indolostilbene construction

A FeCl(3)-promoted highly atropodiastereoselective cascade reaction: synthetic utility of radical cations in indolostilbene construction

The FeCl(3)-promoted oxidative cyclization/coupling of acetamidostilbenes possessing 3-methoxy, 4-methoxy and 3,5-methoxy substitutions (21), (22) and (23) is described. Only 3,5-substitution gave rise to novel indolostilbenes, each possessing two stereogenic axes (axially chiral but racemic dimers...

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Bibliographic Details
Main Authors: Ahmad, Kartini, Thomas, Noel Francis, Mukhtar, Mat Ropi, Noorbatcha, Ibrahim Ali, Weber, Jean-Frederic Faizal, Nafiah, Mohd Azlan, Velu, Saraswati S, Takeya, Koichi, Morita, Hiroshi, Lim, Chuan-Gee, A Hadi, A Hamid, Awang, Khalijah
Format: Article
Language:English
Published: Elsevier BV 2009
Subjects:
TP248.13 Biotechnology
Online Access:http://irep.iium.edu.my/12797/1/A_FeCl3-promoted_highly_atropodiastereoselective_cascade_reaction_synthetic.pdf

Internet

http://irep.iium.edu.my/12797/1/A_FeCl3-promoted_highly_atropodiastereoselective_cascade_reaction_synthetic.pdf

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