Two plus four equals three - iron(II)/iron(IV) comproportionation as an additional pathway for iron(IV)-oxido reactions
Iron enzymes are ubiquitous in nature. In particular, enzymes with iron−oxygen cofactors as active sites perform a vast variety of reactions. Both iron(III)-hydroxido and iron(IV)-oxido species have been observed to play a catalytically active role. In order to complement biochemical investigations,...
| Main Authors: | , , , , , , , , , , , , , , |
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| Format: | Article |
| Published: |
American Chemical Society (ACS)
2025
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| Subjects: |