In search of a new class of stable nitroxide: synthesis and reactivity of a peri-substituted N,N-bissulfonylhydroxylamine

Acyclic bissulfonylnitroxides have never been isolated, and degrade through fragmentation. In an approach to stabilising a bissulfonylnitroxide radical, the cyclic, peri-substituted N,N-bissulfonylhydroxylamine, 2-hydroxynaphtho[1,8-de][1,3,2]dithiazine 1,1,3,3-tetraoxide (1), has been prepared by f...

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Bibliographic Details
Main Authors: Patel, Bhaven, Carlisle, Julie, Bottle, Steven E., Hanson, Graeme R., Kariuki, Benson M., Male, Louise, McMurtrie, John C., Spencer, Neil, Grainger, Richard S.
Format: Article
Language:English
Published: Royal Society of Chemistry 2011
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Online Access:https://repository.londonmet.ac.uk/1045/1/c0ob00976h.pdf