Structural isomers of a terminal phosphinidene complex

The reactions of ArP(Li)(SiMe3)(Ar = 2,4,6-But3C6H2) with (η5-C5H5)2ZrCl2 and (η5-C5H4Me)2WCl2 afford (η5-C5H5)2Zr(Cl)P(SiMe3)(Ar) and two isomers of composition (η5-C5H4Me)Ar)], respectively, the structures of which have been determined.

Bibliographic Details
Main Authors: Arif, Atta M., Cowley, Alan H., Nunn, Christine M., Pakulski, Marek
Format: Article
Language:English
Published: Royal Society of Chemistry 1987
Subjects:
Online Access:https://repository.londonmet.ac.uk/740/2/Structural%20Isomers%20of%20a%20Terminal%20Phosphinidene%20Complex.pdf