Room temperature DBN initiated phospha‐Brook rearrangement of α‐hydroxyphosphonates to phosphates
A series of substituted aryl phosphate esters have been synthesized from their α‐hydroxyphosphonates substrates, using DBN (1,5 diazabicyclo(4.3.0)non‐5‐ene) at room temperature, via a phospha‐Brook rearrangement. The aryl‐substrate dependence of the rearrangement was explored, and excellent yields...
| Main Authors: | , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Chemistry Europe ; Wiley-Blackwell
2022
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| Subjects: | |
| Online Access: | https://repository.londonmet.ac.uk/8027/1/ejoc.202201101.pdf |