Mesoionic carbenes in low- to high-valent vanadium chemistry

We report the synthesis of vanadium(V) oxo complex 1 with a pincer-type dianionic mesoionic carbene (MIC) ligand L1 and the general formula [VOCl(L1)]. A comparison of the structural (SC-XRD), electronic (UV–vis), and electrochemical (cyclic voltammetry) properties of 1 with the benzimidazolinyliden...

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Bibliographic Details
Main Authors: Neururer, Florian R., Lyu, Shenyu, Leitner, Daniel, Baltrun, Marc, Fisher, Katherine R., Kopacka, Holger, Wurst, Klaus, Daumann, Lena J., Munz, Dominik, Hohloch, Stephan
Format: Article
Language:English
Published: American Chemical Society 2021
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Online Access:https://repository.londonmet.ac.uk/9958/1/neururer-et-al-2021-mesoionic-carbenes-in-low-to-high-valent-vanadium-chemistry.pdf