Spin delocalization in the radical cations of porphyrin molecular wires: A new perspective on EPR approaches

The spin delocalization in the radical cations of a series of ethyne-linked oligoporphyrins was investigated using EPR spectroscopy. The room-temperature spectral envelope for these oligomers deviates significantly from the benchmark N–0.5 trend in line width expected for a completely delocalized sp...

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Bibliographic Details
Main Authors: Moise, G, Tejerina, L, Rickhaus, M, Anderson, H, Timmel, C
Format: Journal article
Language:English
Published: American Chemical Society 2019