Substitution chemistry of sterically demanding boryl ligands
The synthetic and reaction chemistry of the asymmetric aryl(bromo)boryl complexes (η5- C5H5)Fe(CO)2B(Ar)Br [Ar = 2,4,6-Me3C6H2, Mes (3); 2,6-(2,4,6-iPr3C6H2) C6H3, 2,6-Trip2C6H3 (4)] are reported. In particular, the scope for substitution at boron by main-group nucleophiles is probed. The synthesis...
| Main Authors: | , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2003
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