Sterically Encumbered Iridium Bis(N-heterocyclic carbene) Complexes: Air-Stable 14-Electron Cations and Facile Degenerate C-H Activation

Sterically Encumbered Iridium Bis(N-heterocyclic carbene) Complexes: Air-Stable 14-Electron Cations and Facile Degenerate C-H Activation

Cationic Ir(III) systems supported by a bis(expanded NHC) framework and featuring both agostic C-H and cis alkyl/hydride ligand sets have been targeted by protonation of the corresponding bis(alkyl) hydride complexes. Remarkably, the steric shielding afforded by the NHC substituents is such that the...

وصف كامل

التفاصيل البيبلوغرافية
المؤلفون الرئيسيون:	Phillips, N, Rowles, J, Kelly, M, Riddlestone, I, Rees, N, Dervisi, A, Fallis, I, Aldridge, S
التنسيق:	Journal article
اللغة:	English
منشور في:	2012

مواد مشابهة

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