Structural and magnetic conformation of a cerocene [Ce(COT′′)2]− exhibiting a uniconfigurational f1 ground state and slow-magnetic relaxation
Magnet-like behaviour, in the form of slow relaxation of the magnetization, was observed for a monometallic cerium(III) sandwich complex. The use of trimethylsilyl substituted COT ligands (COT′′) led to the formation of a staggered COT′′ arrangement in the cerocene-type sandwich complex with a well-...
| Hauptverfasser: | , , , , |
|---|---|
| Format: | Journal article |
| Veröffentlicht: |
Royal Society of Chemistry
2013
|