Group 5 hydride and borohydride complexes supported by cyclopentadienyl-imido ligand sets.
Reactions of Cp*Ta(NAr)Cl2 and CpM(NAr)Cl2 (M = Nb, Ta; Ar = 2,6-C6H3(i)Pr2) with NaBH4 in the presence of an excess of PMe3 provided facile access to the corresponding dihydride derivatives Cp(R)M(NAr)H2(PMe3) (Cp(R) = Cp, Cp*). Reaction of Cp*Nb(NAr)Cl2 with NaBH4 in the absence of phosphine gave...
| Main Authors: | , , , , |
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| 格式: | Journal article |
| 语言: | English |
| 出版: |
2014
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