Mechanistic Study of a Ru-Xantphos Catalyst for Tandem Alcohol Dehydrogenation and Reductive Aryl-Ether Cleavage

We employ density functional theory (DFT) calculations and kinetics measurements to understand the mechanism of a xantphos-containing molecular ruthenium catalyst acting on an alkyl aryl ether linkage similar to that found in lignin to produce acetophenone and phenol. The most favorable reaction pat...

詳細記述

書誌詳細
主要な著者: Chmely, S, Kim, S, Ciesielski, P, Jimenez-Oses, G, Paton, R, Beckham, G
フォーマット: Journal article
言語:English
出版事項: 2013