Mechanistic Study of a Ru-Xantphos Catalyst for Tandem Alcohol Dehydrogenation and Reductive Aryl-Ether Cleavage
We employ density functional theory (DFT) calculations and kinetics measurements to understand the mechanism of a xantphos-containing molecular ruthenium catalyst acting on an alkyl aryl ether linkage similar to that found in lignin to produce acetophenone and phenol. The most favorable reaction pat...
主要な著者: | Chmely, S, Kim, S, Ciesielski, P, Jimenez-Oses, G, Paton, R, Beckham, G |
---|---|
フォーマット: | Journal article |
言語: | English |
出版事項: |
2013
|
類似資料
-
A Mechanistic Investigation of Acid-Catalyzed Cleavage of Aryl-Ether Linkages: Implications for Lignin Depolymerization in Acidic Environments
著者:: Sturgeon, MR, 等
出版事項: (2014) -
Mechanistic studies of the dehydrocoupling and dehydropolymerization of amine-boranes using a [Rh(Xantphos)]⁺ catalyst.
著者:: Johnson, H, 等
出版事項: (2014) -
Mechanistic studies of the dehydrocoupling and dehydropolymerization of amine-boranes using a [Rh(Xantphos)]⁺ catalyst
著者:: Johnson, H, 等
出版事項: (2014) -
Activity of heterogeneous supported Cu and Ru catalysts in acceptor-less alcohol dehydrogenation
著者:: Kamila Kaźmierczak, 等
出版事項: (2021-01-01) -
Transition metal pincer catalysts for formic acid dehydrogenation: a mechanistic perspective
著者:: N. Sai Kumar, 等
出版事項: (2024-08-01)