Modulation of σ-alkane interactions in [Rh(L2)(alkane)]+ Solid-State Molecular Organometallic (SMOM) systems by variation of the chelating phosphine and alkane: Access to η2,η2-σ-alkane Rh(I), η1-σ-alkane Rh(III) complexes, and alkane encapsulation

Modulation of σ-alkane interactions in [Rh(L2)(alkane)]+ Solid-State Molecular Organometallic (SMOM) systems by variation of the chelating phosphine and alkane: Access to η2,η2-σ-alkane Rh(I), η1-σ-alkane Rh(III) complexes, and alkane encapsulation

Solid/gas Single–Crystal to Single–Crystal (SC–SC) hydrogenation of appropriate diene precursors forms the corresponding σ–alkane complexes [Rh(Cy2P(CH2)nPCy2)(L)][BArF4] (n = 3, 4) and [RhH(Cy2P(CH2)2(CH)(CH2)2PCy2)(L)][BArF4] (n = 5, L = norbornane, NBA; cyclooctane, COA). Their struc-tures, as de...

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Bibliographic Details
Main Authors: Martinez-Martinez, AJ, Tegner, BE, McKay, AI, Bukvic, AJ, Rees, NH, Tizzard, GJ, Coles, SJ, Warren, MR, Macgregor, SA, Weller, AS
Format: Journal article
Published: American Chemical Society 2018

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