Probing competitive and co-operative hydroxyl and ammonium hydrogen-bonding directed epoxidations
The diastereoselectivities and rates of epoxidation (upon treatment with Cl3CCO2H then m-CPBA) of a range of cis- and trans-4-aminocycloalk-2-en-1-ol derivatives (containing five-, six-, and seven-membered rings) have been investigated. In all cases where the two potential directing groups can promo...
Main Authors: | , , , , , , , , , |
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Format: | Journal article |
Language: | English |
Published: |
American Chemical Society
2017
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