Oxapolycycles from one-pot cross-metathesis/carbonyl ylide formation-intramolecular cycloaddition of alpha-diazo-beta-keto esters

Chemoselective cross-metathesis of unsaturated α-diazo-β-keto esters using Grubbs' 2nd generation catalyst, followed by Rh 2(OAc)4-catalysed tandem carbonyl ylide formation-intramolecular cycloaddition is demonstrated. The two different catalytic metallocarbene transfer reactions have also been...

詳細記述

書誌詳細
主要な著者: Hodgson, D, Angrish, D
フォーマット: Journal article
言語:English
出版事項: 2006