Oxapolycycles from one-pot cross-metathesis/carbonyl ylide formation-intramolecular cycloaddition of alpha-diazo-beta-keto esters
Chemoselective cross-metathesis of unsaturated α-diazo-β-keto esters using Grubbs' 2nd generation catalyst, followed by Rh 2(OAc)4-catalysed tandem carbonyl ylide formation-intramolecular cycloaddition is demonstrated. The two different catalytic metallocarbene transfer reactions have also been...
| Hlavní autoři: | , |
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| Médium: | Journal article |
| Jazyk: | English |
| Vydáno: |
2006
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