A β-diketiminate-stabilized sila-acyl chloride: systematic access to base-stabilized silicon analogues of classical carbonyl compounds

An oxidation/substitution strategy for the synthesis of silicon analogues of classical organic carbonyl compounds is reported, by making use of a novel β-diketiminate-supported sila-acyl chloride-the first example of such a compound isolated without the use of a stabilizing Lewis acid. Nucleophilic...

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Detalhes bibliográficos
Principais autores: Do, D, Protchenko, A, Ángeles Fuentes, M, Hicks, J, Kolychev, E, Vasko, P, Aldridge, S
Formato: Journal article
Idioma:English
Publicado em: Wiley 2018