The influence of phosphine cone angle on the synthesis and structures of [Rh(PR3)(Binor-S)]+ complexes that show C-C sigma interactions
Complexes that show C-C···Rh sigma interactions have been synthesized and characterised by NMR spectroscopy and X-ray diffraction: [Rh(PR3)(Binor-S)][BArF4], R = P tBu2Me, PCy2Ph; Ar = C6H 3(CF3)2, Binor-S = 1,2,4,5,6,8-dimetheno-S- indacene. These studies, in concert with previously published work,...
| Main Authors: | , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2013
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