Electron transfer and catalytic control by the iron-sulfur clusters in a respiratory enzyme, E. coli fumarate reductase.

Factors governing the efficacy of long-range electron relays in enzymes have been examined using protein film voltammetry in conjunction with site-directed mutagenesis. Investigations of the fumarate reductase from Escherichia coli, in which three Fe-S clusters relay electrons over more than 30 A, l...

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Bibliographic Details
Main Authors: Hudson, J, Heffron, K, Kotlyar, V, Sher, Y, Maklashina, E, Cecchini, G, Armstrong, F
Format: Journal article
Language:English
Published: 2005